Yes it can.
Have a look at this: Understanding and Configuring Outbound Policy
When a PepVPN tunnel is up, each end advertises known subnets to the other, so you typically don’t need to add destination routes (because they have been learnt already). If however you want to get to a distant hop then you might so in the case of:
SiteA 192.168.50.0/24 Site B 192.168.1.0/24 WAN <3rd party Layer 3 network with its own dynamic routing table> Site C 10.10.1.0/24
You would add an outbound policy to Site A sending all traffic for 10.10.1.0/24 via the PepVPN.